Search results for "Molecular simulations"

showing 2 items of 2 documents

Kirkwood-Buff integrals from molecular simulation

2019

The Kirkwood-Buff (KB) theory provides a rigorous framework to predict thermodynamic properties of isotropic liquids from the microscopic structure. Several thermodynamic quantities relate to KB integrals, such as partial molar volumes. KB integrals are expressed as integrals of RDFs over volume but can also be obtained from density fluctuations in the grand-canonical ensemble. Various methods have been proposed to estimate KB integrals from molecular simulation. In this work, we review the available methods to compute KB integrals from molecular simulations of finite systems, and particular attention is paid to finite-size effects. We also review various applications of KB integrals comput…

Work (thermodynamics)010405 organic chemistryChemistryGeneral Chemical EngineeringIsotropySolution theoryStructure (category theory)Finite systemGeneral Physics and AstronomyMolecular simulation02 engineering and technology01 natural sciences0104 chemical sciencesKirkwood-Buff integrals020401 chemical engineeringVolume (thermodynamics)Statistical physicsKirkwood-Buff theoryMolecular simulations0204 chemical engineeringPhysical and Theoretical ChemistryDensity fluctuationsSmall system methodFluid Phase Equilibria
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The role of SAXS and molecular simulations in 3D structure elucidation of a DNA aptamer against lung cancer

2021

Aptamers are short, single-stranded DNA or RNA oligonucleotide molecules that function as synthetic analogs of antibodies and bind to a target molecule with high specificity. Aptamer affinity entirely depends on its tertiary structure and charge distribution. Therefore, length and structure optimization are essential for increasing aptamer specificity and affinity. Here, we present a general optimization procedure for finding the most populated atomistic structures of DNA aptamers. Based on the existed aptamer LC-18 for lung adenocarcinoma, a new truncated LC-18 (LC-18t) aptamer LC-18t was developed. A three-dimensional (3D) shape of LC-18t was reported based on small-angle X-ray scattering…

oligonucleotideMolecular modelAptamer610RM1-950chemistry.chemical_compoundDrug DiscoveryA-DNAddc:610Binding siteOligonucleotideaptamerSAXSspatial structurelung adenocarcinomamolecular dynamicsProtein tertiary structurefragment molecular orbitalchemistrysmall-angle X-ray scatteringBiophysicsMolecular MedicineOriginal Articletertiary structureTherapeutics. Pharmacologymolecular simulationsDNAFragment molecular orbital
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